X-ray Notation: Difference between revisions

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In X-ray spectroscopy and other X-ray characterization techniques, a special form of notation is used to indicate atomic orbitals and the movement of electrons between discrete energy levels when interacting with X-ray radiation. This nomenclature is known as X-ray notation and Siegbahn notation, as opposed to the spectroscopic notation (1s, 2s, 2p, 3s, 3p, 4s, 3d, ... ) used in most areas of chemistry.
In X-ray spectroscopy and other X-ray characterization techniques, a special form of notation is used to indicate atomic orbitals and the movement of electrons between discrete energy levels when interacting with X-ray radiation. This nomenclature is known as X-ray notation and Siegbahn notation, as opposed to the spectroscopic notation (1s, 2s, 2p, 3s, 3p, 4s, 3d, ... ) used in most areas of chemistry.
== Notation Translation ==
== Notation Translation ==
{| class="wikitable"
{| class="wikitable"; text-align: center; width=500px;
! colspan="3" |Quantum numbers
! colspan="3" |Quantum numbers
! rowspan="2" |Spectroscopic notation
! rowspan="2" |Spectroscopic notation

Revision as of 17:55, 10 July 2021

In X-ray spectroscopy and other X-ray characterization techniques, a special form of notation is used to indicate atomic orbitals and the movement of electrons between discrete energy levels when interacting with X-ray radiation. This nomenclature is known as X-ray notation and Siegbahn notation, as opposed to the spectroscopic notation (1s, 2s, 2p, 3s, 3p, 4s, 3d, ... ) used in most areas of chemistry.

Notation Translation

Quantum numbers Spectroscopic notation X-ray notation
1 0 1/2 1s K (K1)
2 0 1/2 2s L1
1 1/2 2p1/2 L2
3/2 2p3/2 L3
3 0 1/2 3s M1
1 1/2 3p1/2 M2
3/2 3p3/2 M3
2 3/2 3d3/2 M4
5/2 3d5/2 M5
4 0 1/2 4s N1
1 1/2 4p1/2 N2
3/2 4p3/2 N3
2 3/2 4d3/2 N4
5/2 4d5/2 N5
3 5/2 4f5/2 N6
7/2 4f7/2 N7